Preheat the oven to 400. Line a baking sheet with parchment or a silicone liner, then spray with cooking spray.
Cut each of the chicken breasts in half horizontally to form two thinner fillets from each breast. Drizzle the fillets with the olive oil and toss to coat. In a shallow dish or large plate, whisk together the bread crumbs, panko, salt, parsley, basil, and garlic powder.
Dip the chicken fillets in the bread crumb mixture, pressing gently to coat. Place on the prepared baking sheet, and spray the tops with cooking spray.
Bake 20-25 minutes, or until golden brown and crispy, and cooked through.
Spread a few tablespoons of marinara sauce over each chicken breast, and top with a slice of provolone cheese. Sprinkle with the grated parmesan cheese. Return to the oven for 10 minutes, or until the cheese is melted and bubbly. Serve hot.